Can you tell me what CPU you have? If you want to make partitions larger than 2 TB you have to install 64 bit OS. not every 775 CPU will support it.
OK You have few options mate:
1. live your old server a side and build a new one.
Find board with 6 or 6+4 sata ports...than install 64 bit OS Win7x64 works fine. I recommend 2 install it on a non raid drive. Than create your R5 array on Intel ports, and if you will buy MB with 4 non Intel ports you can use them 4 strip or spend.
2. use xp 32 and migrate your cards and raid.
Create your R5 on Intel ports, but you can't go over 2tb
3. buy NAS
few notes:
hard drive choice is important....make sure that the drive works with no issues in raid configurations. If you get non raid hard drive like...