Are you sure the plug really fits. 6 pin atx 12v is strange thing.
Video cards use what is called PCIE which is has a different layout than atx. They are keyed to prevent you from actually plugging the wrong things in. Both might be 8 pins but plastic housing are different. You will see some are square and other have a rounded top.
Google is being bad this morning can't link the best image I found to show this.
Looking a the manual the 6 pin connector on that motherboard looks like the 8 pin ATX connector with 2 pins removed. It is not the same as video card.
Now technically everything is just 12 volts or ground on both types of connectors so you could get a adapter and run a motherboard off a video card connector. You need to be very careful the plastic pins are keyed to prevent people from destroying their equipment by connecting voltage and grounds to the wrong stuff.