So as soon as you plug in the computer it turns on by itself, and won't turn off unless you unplug it?
Make sure you only have standoffs where they should be underneath the motherboard, to ensure nothing is shorting the board.
A bad PCI card can cause this problem as well. You can try removing them one by one and see if the problem goes away. (Obvisuly don't remove them while it is on!)
My Desktop: <A HREF="http://Mr5oh.tripod.com/pc.html" target="_new">http://Mr5oh.tripod.com/pc.html</A>