I'm going to assume SMPS means Semi-Modular Power Supply, if this is wrong please correct me.
If it only has old molex leads, there are molex to sata power connector adapters, but in my experience they are poor substitutes that lack a voltage, 3.3V, but the biggest issue is they tend to have a poor fit and can short out easily.
I would recommend getting a newer power supply if this is the case, it will have native SATA support, probably be more efficient, and less likely to fail because of age. Power supplies over five years old are going to be prone to problems and if it goes faulty it could damage other components.