It would allow you to set up SLI like that, but would perform very very badly. Easiest answer is to not do it. The cards in SLI will render every other frame, and when you throw one in thats not the same as the other, it messes up the process pretty badly. Check out the tom's articles on how SLI works to get a better explanation.
Best bet would be to try your hardest to find another 460SE, or buy a better single card like a 560 ti or 6870