Hey Tren,
NO do not install your O/S on the slave. If you do, the 2 drives will fight between each other and cause you major grief and unrest. All you have to do is make sure your ata drive is set to "slave" (most hdd's come with a diagram of sorts to indicate how to set the jumpers), once that is done, plug in the drive, go into the bios to make sure your mobo "SEE'S " this new drive.
Depending on what type of drive it is, you should go to the website of the drive (Maxtor, WD, SEagate, etc) and download the install and utility drivers for it.
YOu will then have to "initialize" it and format it before you can start to use it. Once the utility has completed it's formatting, you can now use it to move files and whatever to your new drive.
Hope this helps and if you have any trouble, send another post and I can help you further. I will whatch out for the post this evening ok?