Nope. First off ANY drive that is in a RAID is NOT a backup it is a Redundancy Fail Over. There is a difference.
BUT in your case this is how you would acheive what you want.
Make a RAID 0 of two drive (MUST BE HARDWARE RAID!)
Then make a Software RAID 1 in Device manager of that RAID 0 (Which will be shown as one drive) and then make a new mirrored volume with the other drive (MUST be the same size or bigger as the main RAID 0
That is how you would do what you want.
otherwise adding 1 more drive gives you a RAID 10. It is a RAID 0 of Two RAID 1's. So as long as both drives in the same RAID on don't fail you will be fine. What i said above is NOT a raid 10 as a RAID 4 requires min 4 drives, adding 2 drives to keep expanding, of the same size.
Honestly though I would make the so called backup drive its own drive and use a program like Macrium Reflect to clone it over. The reason being, and this is why RAID, even RAID 1 is NOT a backup, is if the file system get corrupt, or a file is delete etc, its gone on BOTH drives. That is NOT a backup.