No, r0 means you multiply by two, that means, if you had two 128GB drives, you'd get a 256GB r0 drive. But as you said, one SSD is 64GB and the other is 128GB, means you'll get 64GB+64GB=128GB.
Raid 0 is dividing ALL data into two halves, and you can see the problem if one SSD was allowed to keep its entire size, you'd end up with only half the data on the excess 64GB the 128GB has compared to the other SSD.