If the ram works, you are good.
More ram will usually trump faster ram.
With some motherboards, you will still get dual channel operation with the original ram across two channels, and the odd capacity will be in single channel mode.
But... and a big but.
Adding ram is not 100% guaranteed to work.
Ram is sold in kits for a reason.
A motherboard must manage all the ram using the same specs of voltage, cas and speed.
The internal workings are designed for the capacity of the kit.
Ram from the same vendor and part number can be made up of differing manufacturing components over time.
Some motherboards, particularly AMD can be very sensitive to this.
This is more difficult when more sticks are involved.
That is why ram vendors will NOT...