Is this is the spec sheet for your pc?
https://i.dell.com/sites/csdocument...ments/en/us/optiplex-390-spec-sheet-final.pdf
If so, your ram options is limited to two sticks of ddr3 1333 ram totaling 8gb.
It should be cheap to add a second stick like what you have.
Go to crucial or kingston sites and access their ram upgrade advisor.
Enter your pc info and you will get a list of supported upgrades.
Failing that, run cpu-Z and access the spd tab.
You will see what ram specs you now have installed.
Try to buy a stick with the exact same specs.
DDR3, speed, voltage, timing.
Intel is mostly tolerant of mismatched DDR3 ram if you need to go that way.
Otherwise buy a 2 x 4gb kit which will be matched.