In order to run dual-channel, the memory configuration on each channel must be a nearly exact match as far as the memory controller is concerned. You cannot have 2x4GB on one channel and 1x4GB on the other and the timings/clocks cannot be different for any module. (Although it is usually possible to down-clock faster modules to match the slowest.)
If you want to run dual-channel, you will have to ditch your current 4GB or get a second matching 4GB DIMM.
You can still run dual-channel with asymmetrical configuration but the memory controller will run them in interleaved mode which usually does not perform as well.