The Intel RST(Rapid Store Technology) software allows you to set the amount of the SSD to use, What is left is able to be used as you see fit.
The catch here is the software runs once in windows. So my guess is it would be interesting to setup.
I could try it just before my Win8 trial expires(currently on a 64gigabyte SSD I had purchased for SRT. Honestly it worked well enough) as messing that up would not hurt things
I was always guessing it would be more easy to set it up on another computer as Intel raid volumes carry over when moving drives from system to system. Then install windows on the extra space made available.
I just have never tried it and with a larger SSD, my FIRST option would always be to install windows on it.
What are you using the HDD for anyway?
My media center has a 128gigabyte M4 + 1tb HDD(5400 rpm notebook drive) and this system works very well for my use(I do have some games installed on this system.).
Keep in mind of course if you are MASSING games, then you would either have to move games off to the hard drive OR pic what games you want the speed on.
Ok. I will use the hard drive for main storage"pictures, videos, music, etc" and install Microsoft office on the hard drive, I don't really care for speed with Microsoft Office, and the ssd is going to have Windows, web browsers, games, Sony Vagas, and the hardware drivers.
SRT would have to deal with the same issue. less played games would not get the cache performance boost.
You can actually install ALL games on the hard drive then create a folder on the SSD(Lets say c : \ games \) and use a junction("mklink" or "Link Junction Magic" among many other programs available to make this VERY easy) to make a link and copy(its a simple copy + paste then make the link) to games(or programs) you are wanting speed from. Then when you are not playing it any more, you can just break the junction and copy it back to the hard drive.
All this time windows will THINK the games(or even programs) are on the HDD, but they will perform like they are on the HDD.
I have made LOTS of use of junction points with my HDD/SSD setups and made a quick guide to show users how to do it. This should be enough to get anyone started. I still have lots of junctions just to keep all my steam games evenly across my SSD's on my other system(it used to keep the current ones on the SSD when I had SSD + HDD).
This approach lets YOU control what gets the speed, but should NOT be used to move parts of windows from drive to drive(for clear stability reasons).
I posted a link from another forum member as well(it is the second link in my guide right above "Why would I want to do this? ") to move the full USERS folder to the hard drive. This can save SSD space and also reduce unwanted write cycles.
http://www.tomshardware.com/forum/294557-32-guide-move-software-games-drive-reinstalling