SSDs aren't as reliable for long-term storage as HDDs, a recent study shows that SSDs may lose data when powered off for long periods of time, however much solid state storage you have, you need at least as much in magnetic for backups.
You can't simply add another SSD and expect it to run in RAID without wiping the data on the other drive first, so you will need magnetic storage anyway during that process. Not that I really recommend using RAID0 ever, but that's just me, if you absolutely need 1000MB/s+ reads for heavy work get an Intel 750 instead, it's still not worth the risk factor to RAID.