When using an Ivy Bridge Processor the three PCIe 3.0 x16 slots of the MSI Z77A-GD65 have the following possible support options:
x16/x0/x0
x8/x8/x0
x8/x4/x4
That means that 2-way SLI is the maximum supported. For the graphics card to be included in the SLI set the x16 slot must have a minimum of 8 PCIe lanes and only two of the three x16 slots on that motherboard have at least 8 PCIe lanes or more.