If we assume the graphics card is the bottleneck, and it probably is, then the MAXIMUM frame per second would be:
797/772
Which is 3%.
However I've tested this concept and your lucky to get a maximum of 2% due to the graphics card architecture (it's pretty complicated). Also, it only matters if you aren't capped, and you really should be attempting to run most games at 60FPS with VSYNC enabled. 60FPS is because that's the maximum most monitors can display and VSYNC is to synchronize updating the screen so you don't get tearing of the screen.
(VSYNC and Anti-Aliasing can be forced for AMD cards using RadeonPro if a game, like Mass Effect 1 or 2 doesn't support it; for ME use 4xAA SuperSampling if possible. Awesome tool. The only game I was unsuccessful was Witcher #1 and ATITraytools worked for it.)
So ignore such a small increase and look at PRICE, QUALITY and COOLING (NOISE). Also be aware of the recent micro-stuttering article. In otherwords, stay away from SLI or Crossfire.
If you really need a GTX580 then I'd be careful about the noise level so compare. My advice personally would be to get either a GTX560Ti or GTX570.
Be aware of the following, upcoming cards which use a 28nm process and will be roughly 2.5 to 3x the performance for the same power (which means MUCH, MUCH QUIETER):
AMD 7000 series (Q4 2011)
NVidia 600 series (Q2 2012)
I already have an HD5870, but money's no issue, however noise and micro-stuttering are. I have a few games that would benefit from a better card. Actually, it's annoying that even with only one graphics card I still get stuttering and other issues even at 60FPS.
Anyway, I intend to buy an NVidia card, hopefully in April 2012 which performs about 3x as well as my current HD5870. It's recommended to get more than 1GB for single-GPU cards because upcoming games will be using more VRAM. 1.5GB would likely be plenty.
I like AMD, however it seems that in general NVidia is getting slightly better results with improved drivers and talking to the video game companies. As well there's the whole PhysX issue. I only got the HD5870 (which is still great) because at the time the NVidia 400 series was far too hot and loud forcing a redesign which became the 500 series.