I think the main issue with allowing something other than water to dissolve the PCB is that it still requires an active step to initiate the process. Most people are just going to throw whatever the device is into the trash without doing anything else when they're done with it, which in that case is functionally equivalent to not having it be biodegradable in the first place.
Having it dissolved by water at least makes it so that anyone can toss it with there still being some reasonable confidence that it will have a chance to properly biodegrade, but obviously the shortcomings everyone has already pointed out with that make it not really a good idea, so back to square one.
Having a biodegradation process initiated with a different solvent I think could still be useful to augment dedicated disposal/recycling processes, but again, I think most people are just throwing their electronics in the trash, so the majority of e-waste wouldn't benefit from it since those products won't reach the channels for proper disposal anyway.