100% can be completely normal when running a game if the game is programmed efficiently enough to fully use two cores.
What you need to double check is your GPU. Tools like GPU-Z can tell you your GPU usage, it should be under 100% because if it's at 100% then your frame-rate is going to drop.
If you aren't running a game then something is having problems, you can see what is using the CPU in Task Manager. It's not uncommon for Windows to have an issue and one of it's processes will start maxing out the processor.