Windows 7 Ultimate 64bit with XP 32 bit program. Are they compatible?

Gary J

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Dec 21, 2011
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Hello,
I just upgraded to windows 7 Ultimate to utilize the XP mode. I currently access a company thru a VPN client network on my 64 bit Windows. The company has changed some programs that are 32 bit which I have downloaded to XP. Will the 2 systems work together or will I need to access the company from the XP side? Also, is the remote desktop connection something that came with the upgrade?
Thanks Gary