What do you PRIMARILY use the PC for??? That matters.
A 3070Ti is not 'light' - well, I wouldn't consider 300w light. Most aftermarket models will pull more.
Also, open air models dump their waste heat inside the PC, heating up anything above it - sometimes, even things below it(depends if airflow is smooth or turbulent). So, regardless of AIO front or top, SOMETHING is going to be heated up from something else.
Whether a minimal or significant amount, comes down to the power used by the part in question. The heat consumed by a 5800X pales in comparison to what the 3070Ti is capable of. Front mounted cpu AIO with that cpu is nothing. Top mounted, on the other hand, the AIO needs to cope with the cpu and everything below it. You offset that by using larger rads at the top.
AIOs do best when their radiators are placed against open mesh panels.
Solid, or semi-solid panels? You may as well be stacking 2 walls - the radiator itself is a source of air resistance - and reducing the cooler's efficiency.
Deepcool Matrexx has a semi-solid front panel, which isn't ideal for AIO radiators, and it only allows a max of 240mm at the top.
You're kinda screwed out of optimizing cooling either way.
TL;DR: I would suggest completely shelving a cpu AIO here for an air cooler(164mm or shorter)... if you insist on the AIO, then I will lean on front mount, with the fans specifically set to pull air through the rad and inside the chassis.
Avoid pushing air through the rad into the chassis - it will not be as effective.