I have a Mini-ITX motherboard, so I have only one PCI Express slot. I would need a second one though, are there any adapters/converters that would allow me to add an extra one?
Yes, is the answer to your question !. I found one on Ebay... here it is.
http://www.ebay.co.uk/itm/262371498163 It connects to your motherboard via the SFF-8643 connector, which most of the new Mini ITX boards have.
There are also PCIE nultiplex boards available, but they reduce the band width. So a single PCIEx16 becomes 4 x PCIEx4. However, if you want to use one of the slots for a PCIE SSD, your far better just getting one of the Intel 2.5" versions with an adapter which connects directly to the SFF-8643.