As suspected.
You have the OS on a 32GB drive. Not part of a hybrid.
Initially, that 32GB may have been simply a cache for one of the other drives. Somehow it got disconnected from the cache concept, and now it is an individual drive.
Even worse, 9.5GB is carved off for a recovery partition. Leaving only 19.4GB for the actual OS.
Obviously, that is too small, no matter what you do with it. Just using the system will cause the space to be consumed and released.
So....
Either somehow remarry that back with its original HDD as a cache
or
Just dump that teeny 32GB SSD. Install the actual OS on one of the HDD's.
How was the system configured initially? Did you build this, or is it a prebuilt from somewhere?