Well, unless you just want them so you can say "I have EXPO memory" it's kind of pointless. It is exactly the same thing as what is called XMP, A-XMP, AMP and D.O.C.P. It is simply the onboard profile and pretty much all memory kits have one. So really it is nothing more than a marketing gimmick giving a different name to something that already existed under other names. The names don't make the least bit of difference. All that matters is that the kit be compatible with a given motherboard and that it has an advertised speed and timings which are favorable towards your preferences or requirements.
As far as availability, nothing is EVER available on day one usually. These are generally paper launches for most companies when they announce on a certain date, although the new Ryzen parts are actually in retailers hands right now today so. But as far as the G.Skill Trident Z5 Neo and Flare X5 kits with EXPO profiles, it does not look like they have made it to any retailers pages yet and PCPP does not show any listings for them yet either. I'd give it maybe a week if you MUST have one of these kits as most retailers are probably placing priority on getting the Ryzen parts ramped up before worrying about anything else new. Or, they may simply have not received them yet as there are still abundant delays in a lot of shipping right now, especially from overseas. There have also been several named storms raging in the Atlantic, Pacific and Gulf regions so there might be delays from products coming overseas due to those reasons as well.