Could it possibly be that the FX 8350 is 8 cores/ 8 threads, 125w running under a 200w cooler, vrs a R7 1700x 8 cores/16 threads @180w running under a 300w+ cooler.
You have to understand just how different liquid coolers are from air coolers. Air coolers heat quickly, anything metal does, but it also has finite limits. Even the best aircoolers like the Noctua NH-D15 handily trump any of the 280mm aios, at less than max. This is where aios shine, not in general cooling as much but in maximum ability. That same Noctua will top out much faster, the hotter the cpu gets, the faster it reaches max ability. Liquids are different. That coolant has a far greater ability to absorb heat energy than any air cooler made. So while you are looking at cpu temps, understand that that's just a number, not an indication of performance. The 1700x 16 threads are putting out a massive amount of energy under Aida64 torture, and while you see 66 as a failure, it's still far cooler than the FX 8350 in comparison. If that FX put out 16t, your little aircooler would fry.