tiny voices :
No the NH-D15 would be MUCH better and quieter. It will cool better than the H100i. There are other air options as well that are better in every way.
That is what I would get.
Also why the huge ridiculous case and WAY overpriced PSU?
Change the Case to a Corsair 450D and the PSU to an XFX750.
I was just about to say NH-D15, get that, and 8gb G.Skill Sniper Series 1866mhz Ram, And a Z87 Motherboard, Z97 Is almost pointless as broadwell is a whopping... 3% faster... not so groundbreaking, Also that case as the above said, is way too overkill, unless you plan on pretty mad watercooling, also get the Evga Supernova G2 750/850w Psu instead, A samsung 840 Evo ssd instead of the MX100, and finally a Gigabyte G1 970 Or Zotac Extreme or Omega 970, depending on your budget.