Do NOT use the sensor inside the CPU chip to guide the case ventilation fans. It is ideal to guide the CPU chip cooler, but not the rest of your system. (There are a few cases in which one is forced to use the CPU chip sensor for case fans, but they are uncommon.) Most mobos actually do NOT have access to the temperature of any graphics card components (unless they use a non-standard design) so you normally do NOT have any option to use GPU temperature sensors for case fans.
Many mobos have more than one temperature sensor on the mobo. There is always a "general one" located and intended by the mobo maker to be the best representation of ALL the heat removal needs of mobo components. Extra sensors are intended for use IF you have extra...