Can't say for sure on that router but many run PPPoA to talk to the ISP and then you run PPPOE on the second router. It can be a little hard to setup because you might need things like userid/password or other settings that you would have to get from your ISP web site.
You have a couple options if you do not want to do it that way. You could just leave it. Double NAT really only hurts game consoles that use UPnP. There are a few other things but the all involve running some type of server in your house. You could just leave it and when you have issue then start to worry about this.
You could also try the DMZ option in the sr320n, I assume it has that function. You would just set it to the WAN ip of your new router. This will fix many of the double NAT issues.
Last you could bridge the new router using it as a AP. You would only use the new wifi radios and let the other functions be handled by the sr320n. It depends why you bought the new router I guess if it was just for better wifi then this method will be fine.