1. Can you add RAM? Sure, if you laptop has memory slots. As you don't list make and model of laptop. I couldn't say more than that.
2. No, it would not work in dual channel mode if they are not a match. Most of the time you won't notice the difference or the difference is minor. Having enough RAM in single channel is preferable to insufficient RAM in dual channel. Insufficient RAM leads to page filing, page filing kills performance. Therefore if you can make use of more than 8GB RAM. It would make sense to jump to 12GB or 20GB and have a mismatched set.