I think you mistake what I'm saying, or trying to say. The motors on a DC fan are slightly more robust than on a pwm fan. As a result, DC fans can handle lower voltages better. Most DC fans will drop to 40% or 60% (5v or 7v), whereas pwm fans can have issues at 5v and/or 7v, many pwm won't spin at lower than 9v. (ish)
If you use the DC fan as primary, on the 4pin, it'll read that fan through the tach, so may take the fan down as low as 5v at idle. If the pwm fan on the slave is dropped to a corresponding 5v, it may stop altogether and be constantly trying to start, which can possibly cause damage to the motor as it has volts/amps applied to a single area on the rotor, possibly for hours.
If you use the pwm as primary, it'll only drop as low as the fan can reasonably handle, without tripping any low rpm warnings or stopping.
Control the weakest fan, not the strongest. Control will still be in voltage mode, not pwm, regardless of which fan is primary and slave.