The issue I see is in the fact you assume certain parameters, but leave out others.
As is the assumption the case is a sealed unit and subject only to what the fans can provide. You've most likely discounted/ignored the pressure differentials caused by airgaps at the pci slots, surrounding the fans, between the rad and case, around the side panels etc.
With even the slightest negative pressure case, you'll have @ 14.7psi pushing in every single crevice or crack or gap, if slightly positive you'll have @ 14.7psi + case pressure pushing out of those same cracks.
Also discounted/ignored changing conditions under loads. A case is never at a static pressure, either negative or positive, even a slight change in ratio of fan speeds (seperate headers under seperate controls) will change the pressure inside the case, can even go from a negative to positive differential, or vice versa.
That goes also for temperature gradients. A cold case will be at a different pressure to a warm case, given even identical conditions otherwise.
Math is absolute, except where variables are concerned, so only applies to a single instance. So ppl can say it's positive or negative, based on fan setups and general identity, just like you can say it's warm or cold outside, but specific numbers are beyond calculation unless actually measured in comparison or every single possible variable is either taken out of the equation or accounted for.
That would mean sealing up the case perfectly, knowing expansion/contraction rates of air at specific temps according to specific static pressure and cfm, knowing the exact amount of vacuum applied to the exhaust fan in comparison to the amount of cfm and static pressure applied to the intakes etc etc...
Basically calculating case pressure would be akin to trying to calculate the temp outside, based on sun position, time of day, time of year, current weather and barometric readings etc. Easier just to stick a meter inside and measure the pressure and compare it to ambient pressure.