That's a fascinating and detailed note on voltages and how to interpret.
Regarding your CPU temps, I do not know what they should be for that CPU. But I note than many high-perfornamce CPU's today are designed to oeperate aroung 70C for most loads, and do not start to throttle until the are well over 80C. So, OP, check carefully how YOUR particular CPU SHOULD operate NORMALLY, and at peak load. Your temps may be quite acceptable.
Your tales of pump speed readings still puzzle me. You say when you moved the 3-pin (with one wire only to Pin #3) connector on the wire from the Pump to the PUMP/FAN1 header it gave speed readings which it could not do on the CPU_FAN header. However, the readings were erratic, and 5000 rpm is NOT likely to be correct! That suggests to me that the signals being delivered to that header are "noisy" and inconsistent, causing bad readings. That would indicate a poor connection, so I suggest you get Corsair Tech support involved. THEN you say that, in that condition, the iCUE software utility DID show you quite reasonable and stable Pump speed readings. That is intriguing, for two reasons: (a) why stable when "read' this way, but unstable readings from the SAME signal by a different display; and (b) how did iCUE discover that the PUMP speed signal it was trying to display had MOVED to a different fan header? Moreover, if I read your post right, even before you switched the speed signal cable to that second header, iCue HAD been showing good pump speed signals even though the BIOS screens said they were zero. How could that be?
By the way, I think you have done this but correctly, but want to check. In that AIO system, the RAD FANS are supposed to be plugged into the two fan output connectors on a cable from the Pump. They do NOT connect to any mobo fan header. Done properly, those two fans are controlled solely by the iCue utility, and that is the ONLY place where their speeds can be "seen".