Check the fans on the H100i if you havne't allready, also vacuum the dust out of the case. How long ago was it since you built the system and set the heat sink / cooler to the CPU and are you running an OC? If your running an OC on the system and it's been a several years for the build I would re-apply thermal paste to the cooler. I not sure how you would find out if the cooler is clogged other than making sure your fans are in good shape and spinning an appropriate RPM and re-applying a quality thermal paste, after you have cleaned the cpu surface and the heat-sink surface really well.