As Warp 9 says, CPU load to deliver 60fps is the same regardless of whether you're using a GTX 750 or 1080, and whether the game is on low settings or at max. Your CPU load will be exactly the same, unless you raise graphics sufficiently to lower framerates below what the CPU is capable of. Raising graphics is "free", but you'll get gain more frames than what the CPU can deliver.
That said, I'd expect more performance out of DOTA2 with that i3. I recommend keeping an eye on clockspeed while you're gaming to make sure it isn't throttling.