Good enough, yes,
The balance between cpu and gpu is good,
You can build as is.
Some thoughts:
Those who buy a F suffix processor eventually regret it,
Unless your budget is desperate, spend $25 more for a non f 13100
The 13100 comes with a very good stock cooler.
One can always change out a cooler later.
How many expansion slots will you ever use?
For most of us, it is exactly one for the graphics card.
A MATX sized motherboard will have 4 slots and will be cheaper.
Nobody gaming overclocks any more, they use the default turbo mechanism to boost a couple of cores past what an all core oc can do.
And, a non K processor can not be overclocked anyway.
A B660 or B760 motherboard would be good.
If you might be multitasking while gaming, I would buy a 2 x 16gb kit up front. 5000 speed is fine, Intel does not depend on fast ram for performance.
Ram must be matched in a single kit. That makes adding ram later iffy.
If you can, buy a 2 tb m.2 ssd up front.
I very much like your choice of the corsair rm 750w unit.
It can handle a much stronger future graphics upgrade,
PSU is NOT where you should economize.