If you do want to do some testing of the RAM when your cpu arrives here is what I would do. Use only 2 sticks at a time in dual-channel mode. Your motherboard manual should tell you which DIMM slots to use if only using 2 (or it may not matter). Insert stick A and B. Run a benchmark like Passmark Performance Test. Write down the various scores related to the RAM tests. Next try stick A and C. Repeat test, noting the scores. Then try stick A and D and note the scores. If the RAM test scores are all the same (or very very close), then it doesn't matter which sticks are paired together.
But let's say the test with stick A and D got much better results than the others. Then try B and C together (removing A and D). Those test...