The first thing you should do is investigate the namplate ratings on the '825W' PSU. The GTX 680 is a 195W card: http://www.hwcompare.com/12344/geforce-gtx-680/
That means it will draw 16.25 amps from the +12V rail(s). More at momentary peaks. Be sure your PSU has sufficient capacity on the +12V rail(s) to handle both the wattage and the amperage.
I'm not sure what you mean by a dual SATA, but if the PSU is sufficient, this is what I would recommend for splitting the single 8 pin PCIe connector.
http://www.newegg.com/Product/Product.aspx?gclid=COTi__Sx470CFcdaMgodQl8AwA&Item=N82E16812706022&nm_mc=KNC-GoogleAdwords&cm_mmc=KNC-GoogleAdwords-_-pla-_-Internal+Power+Cables-_-N82E16812706022&ef_id=U02ebAAABGYv50oz:20140415210236:s
But be aware... if the PSU only came with a single 8 pin (150W) connector, it may only be marginal for that class of card. A 'true' 850W PSU would have several 6/8 pin PCIe connectors.