The second PCI Express x16 slot is running at x4; therefore it doesn't meet the SLI specifications. Since you already have it, you could try the old GPU as a physx card, but why would you do that instead of using the 750 Ti? Even if the motherboard supported SLI, it wouldn't make much sense to use such different graphics cards because the latest 750 Ti drivers don't support the 9600 GT.