in all my reading so far I have not come across which is the master GPU. I still have many tabs open i will see if I had missed that.
as far as a hex editor you would not have to know what you are looking at so much as you would just want to compare numbers.
http://mh-nexus.de/en/hxd/
above is a free hex editor and I think it is always a good idea to see what these things look like so you get a better idea of how it works and what they do just for a broader sence of how things a functioning
the link below is a tutorial of sorts that shows a manual bios editting for my series of cards. this link taught me allot and I have read it probably 100 times to just a basic understanding of things
http://translate.google.by/translate?sl=ru&tl=en&prev=_t&hl=ru&ie=UTF-8&eotf=1&u=http://people.overclockers.ru/test2013/17506/Upravlyaem_napryazheniem_videokart_AMD_HD_7_serii_cherez_redaktirovanie_BIOS
if you downloaded them then edited them you should be able flash them.
if you have tried to flash them and it did not work have you used the-unlockbios command. so cards have an extra layer of flash protection that has to be undone first.
So as I am writing I am thinking how to find out which GPU is the primary. I would turn on vsync and run a heaven benchmark which i would think you can run over 60fps. in this scenario if you run hwifo64 you will probably see that one GPU is taking more of the load than the other and I would surmise that the more heavily used GPU is the primary.