The number of connectors you need will depend on your specific components.
You'll obviously need the basics:
24pin ATX connector
4 pin/8 pin CPU connector (4 vs 8 dependent on your motherboard)
Then you'll need the peripheral connectors. This is where it gets complicated. Depending on your video card of choice, each one could require 1 or 2 PCIe 6 or 8 pin connectors. Then you have to look at how many fan headers your motherboard has, is it enough for your cpu cooler plus all your fans? If not then you'll need SATA to fan or Molex to fan adapters or a fan hub (which will probably take SATA power but could also be Molex or PCIe). Then you'll need 1 SATA connector for each drive you have (assuming you are using SATA or SAS drives). Just count it all up and that's how muich you need.
Overall though, the number of connectors isn't something you generally need to worry about. If your PSU is from a reputable manufacturer and of good quality
See this list It probably has the appropriate connectors to connect the average build that would require that much power.
So if you figure out, using PCPartPicker or
http://outervision.com/power-supply-calculator how much power your system needs and pick a PSU that meets those requirements, you have nothing to worry about.
If you still don't trust that just count up the number of power plugs on your selected components and see if they all have connectors from the PSU.
Unrelated, dual-gpu builds are generally inadvisable except in certain edge cases (e.g. no better single GPU available or high core-count computing applications, etc). What's your plan for this build?