Not possible, need realtime Dolby encoding on a hardware level to compress 5.1 audio tracks. Some sound cards do this using Dolby digital live encoding but not sure if your Sony player is able to decode and split the channels. Windows, games don't offer Dolby compressed audio. If were to play dvd movies from PC which contain compressed tracks already on the disc, then maybe you'll get surround.
PC audio is tricky because a lot of the time, Dolby licensing isn't met to save money.
This sound card is able to encode in realtime. Though, if considering, would want to check your Sony can accept 5.1 tracks via optical playing a disc movie from PC.
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Other alternatives which would mean a different audio setup is return your Sony and venture into an Audio Visual Receiver with HDMI inputs and use the Graphics card's audio instead which'll give you hassles 5.1/7.1.