MoFro343,
4th Generation Core i processors do not have a "CPU" temperature sensor. The last processors to have the old analog thermal sensor under the Die was 1st Generation Core i Socket 1366.
SpeedFan, as well as other utilities, don't always correctly label the various sensors, which is not at all unusual. Regardless, the hottest temperatures are at the heat sources near the transistor junction within each of the Cores, where Digital Thermal Sensors (DTS) measure "Core" temperatures.
Throttle temperature for your i5 4570 is 100°C, at which point the processor will automatically reduce Core speed and voltage to safeguard against thermal damage. At 130°C the processor will automatically shut down.
There is no sensor anywhere...