85C would be a horrible idea as the main cap is rated for either 85 or 105C. To run the main cap that close the edge is just a bad idea. 55C with an 85C main cap isn't bad. But if the PSU is rated for 100% output at 50C, and you run it at 55C, that's running it out of spec. Typically you'll see lower output with more temps. So if it's rated for 100% at 50C, you might see it also rated at 90% at 55C, or 90% at 65C. It's hard to find this info however. And every platform will be different. 50C is my hard upper limit simply because that's the common rated temp.
The original green label CX platform was rated for 30C. 55C would probably kill it.