First of all, that PSU is very low end. The 500W rating is peak wattage, meaning if you actually draw 500w for any length of time, the PSU may fail. Also, that PSU only offers 19A on the 12v rail, that's not going to leave much room to spare.
As others have stated, I would not run any modern graphics card, especially one that needs additional power connectors, using a generic power supply like the model you have. A good rule of thumb, if the PSU doesn't have PCI-E connectors, then Its probably not designed to power a system with any decent GPU.
Also, Molex connectors are not designed for powering a graphics card, it's more suited for powering a fan hub or disc drive, things that draw far less power than an enthusiast GPU.
Because of this, I wouldn't recommend using MOLEX to 6 pin adapters.
Using a 750ti with an adapter on this PSU could cause issues, like a dead GPU and other components caused by a failed PSU. Also, sometimes a failed PSU can smoke or even catch fire. This will require your PSU and possibly more components to be replaced. Both of these scenarios will cost more than upgrading your PSU before you use the 750ti, so I would upgrade your PSU to save some headache.
If you want a decent PSU that can easily power that card and has the proper PCI-E power connectors, you don't need to spend much money at all.
You can get a Corsair CX450 80+ Bronze PSU from NewEgg for just $33 (29+ shipping) after rebate. This PSU is modern, 80+ Bronze efficient, good looking, and safe to use with lower power GPUs. It has on average 4.6-star reviews.
This PSU is 450W continuous and offers over 37A on the 12V rail, double your current PSUs rating.
I wouldn't use this PSU for GPUS over a GTX 1660ti due to its wattage, but for a 750ti, the CX450 is more than enough.
https://www.newegg.com/corsair-cx-s...8566&cjevent=730a70a0839911e981c300860a24060d