Yes you can, but you may have issues with the hidden backup partition that Windows 8 creates. I ended up deleting it as it never worked after the cloning, so it became a waste of space.
The other thing you have to make sure of is that the space used on the hard drive is smaller than the size of the SSD. I had to backup a good chunk of my drive to an external before I could clone it. (2tb hd to 256gb ssd)