and the MoBo says up to 1800.
There is no 1800 MT/s DDR3 speeds. What there are, are 1866 MT/s.
When I try to set the RAM from AUTO to 1333 in the BIOS, the PC blue screens on boot. What's going on here?
Then it means, the RAM frequency on that speeds isn't stable.
Just because MoBo supports up to 1866 MT/s DDR3, doesn't mean that EVERY DDR3 RAM, that is 1866 MT/s will work. RAM has to operate at JEDEC standard, which for DDR3, starts from 800 MT/s, then 1066, 1333 and 1600.
Dig up MoBo specs. There, on Support page, there is MoBo memory QVL list, that contains different RAM DIMMs that MoBo manufacturer has tested and confirmed to work at any given frequency.
Sure, RAM that isn't listed in memory QVL can work at it's rated speeds (e.g at 1866 or 1600) but chances of it are 50:50.
Bonus question, he has x2 2GB 1600mhz will he gain anything by putting that in there or would it just confuse things more?
Adding different frequency/timings/capacity RAM to already existing RAM can cause more instability, where entire system won't boot. Or the very least, RAM speed defaults to the slowest stable one.
Here's in-depth guide on why not to combine different RAM DIMMs (the mixed memory chapter),
link:
https://forums.tomshardware.com/faq...y-ram-and-xmp-profile-configurations.3398926/
The PC has x2 4GB DDR3 1333 but in CPUZ it shows the RAM at only 1066mhz.
For DDR3, the RAM frequency doesn't matter. Especially since with higher frequency, you'll get higher latency as well, which nullifies any gains from higher frequency.
Here's a good short vid that explains it well about DDR3 RAM:
View: https://www.youtube.com/watch?v=dWgzA2C61z4
For DDR4 and DDR5, there are sweet spots for RAM frequency but this isn't relevant for your use case.