The ATX12V spec has changed over time, with the 2.0 spec specifying 24 pins,, which include additional +5 and +3.3 ijn the 24 pins. +12V power was increased, R/T changes in delivery for PCIE and other power draw changes, while +3.3 and +5 were reduced.
There were many other changes between ATX12V 1.3 and 2.0. A proper power supply is recommended for what your motherboard supports.