1) You can't just do the OS like that, You would need to clean install all over again to the SSD is the normal / reliable way to do it.
2) Simple step FYI:
Google "Move Steam to Another Drive" and "add SSD step by step"
You can find both youtube videoa and articles on it.
3) The simpliest layout (just follow the logic flow) is to:
A) Get cheap ($45) 1TB Ext Drive
B) Backup your DATA (not system) to the Ext Drive.
C) follow STEAM HDD move instructions to temporarily move to this drive (basic drag and drop of the common folder)
D) make a DBAN CD, wipe the TB, install SSD, insert Windows to install to SSD
E) SPEND ALOT OF TIME installing apps (Office, webborwsers etc.) after going to Windows Store then Windows update to get Windows to Windows8.1 Update version.
F) run SlimDrivers to make sure you have the latest drivers
G) Restore your DATA then follow steps to make the HDD D drive your steam drive
H) NO CLICK CLICK CLICK CLICK CLIK - REPEAT to yoru self NO CLICKY
For now and forever you need to MANUALLY tell Windows when EVER you update / install something at the INSTALL PATH option from C:\Program Files(x86)\ThisSoftware to D:\Program Files (x86)\This Software . Otherwise you will fill your SSD drive in no time flat. NO there is NO automatic way, it is only done manually.
That is it in a nut shell