Non Conductive Liquid for Water Coolers

Solution
No, water is used as it is very special amongst most liquids in that it can move massive amounts of heat energy, nothing else like it, except maybe molten salts, or mercury, which have their own problems. I suppose some flourocarbons might be non-conductive, but they have issues too and their heat capacity isn't great. You don't have a lot of choice, add this to the non maintainability of AIO's and therefore the lack of any proper means of draining and refilling them and you have a problem. You sound like you've never used water before, modifying an AIO is not a good place to start. Not the answer you wanted, but it's the answer.
No, water is used as it is very special amongst most liquids in that it can move massive amounts of heat energy, nothing else like it, except maybe molten salts, or mercury, which have their own problems. I suppose some flourocarbons might be non-conductive, but they have issues too and their heat capacity isn't great. You don't have a lot of choice, add this to the non maintainability of AIO's and therefore the lack of any proper means of draining and refilling them and you have a problem. You sound like you've never used water before, modifying an AIO is not a good place to start. Not the answer you wanted, but it's the answer.
 
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