Multipack
Honorable
Is it toward the bottom right corner? If yes, its the standby light. You need to double check the front panel connectors are in the correct place, as the power on button sounds like it isnt working on your case.
If you have a manual, check the part that says System panel connector (20-8 pin PANEL)). If you dont, look at manual here and make sure they are connected correctly http://dlcdnet.asus.com/pub/ASUS/mb/SocketAM3+/M5A97_LE_R2.0/E8047_M5A97_LE_R20_V2_WEB.pdf?_ga=1.19564415.636118347.1475534542
If you have a manual, check the part that says System panel connector (20-8 pin PANEL)). If you dont, look at manual here and make sure they are connected correctly http://dlcdnet.asus.com/pub/ASUS/mb/SocketAM3+/M5A97_LE_R2.0/E8047_M5A97_LE_R20_V2_WEB.pdf?_ga=1.19564415.636118347.1475534542