Well Vrin should be kept at about .7V above Vcore. Much more and the FIVR will make your CPU run hot, much lower and the FIVR may not be able to deliver your set Vcore under load.
Your temps aren't terrible, what are you stress testing with?
There is always some discrepancy between what you set in the BIOS and what a monitoring utility shows. Also what AIDA64 shows will likely depend on when you are looking at it. Is it under load when you looked at AIDA64 or was it idle. It also depends on what voltage control method you are using: Manual / Static, Adaptive, Offset. I'd guess you are using Static, though I won't assume here.
Did you try 4.3GHz before 4.4GHz? If so what was your Vcore at that frequency? The delta between the two will help us determine if you've hit the wall with respect to Vcore as I mentioned in my last post. If the difference is like 10mV between 4.3GHz and 4.4GHz, and now you've added more than 50mV at 4.5GHz and you still aren't stable, then you might be firmly pressed against the wall. A Vcore of 1.262V is getting close to the limits of AiO coolers and moving into custom loop territory.
As for other settings in the BIOS, it's often recommended to turn off any power save features (C1E, Speedstep, etc). Also if you are using an XMP profile for your RAM, you'll want to set that back down to 1600 or 1333 is even better. Sometimes the IMC will limit your CPU overclock. With these CPU's, the core clockspeed is king, faster RAM is much less beneficial and could limit your core clock overclock.