Yeah, you have a big problem. What is your full system specs including CPU, motherboard, CPU cooler, case, number of case fans, case fan locations, case fan orientations (Intake or exhaust), ETC.
What program are you using for those temps, speedfan? Try another program, I recommend HWinfo:
http://www.hwinfo.com/download.php
It may be that speedfan is reporting inaccurate data or that there is merely a problem with one of the sensors. After looking at your screenshot a second time, it would be pretty unusual for the CPU to be at 33°C and the motherboard at 111. In fact, I'm fairly sure the system would have failed to run before that as the VRMs and northbridge would have likely been too unstable to function.
While some people swear by Speedfan, and maybe it's great for them, I dislike it and am of the opinion that fan controls should be managed in the bios and temps should be monitored with a more modern utility.
Also, if that's speedfan, or whatever it is, make sure you have the MOST recent version installed and that all motherboard chipset drivers are installed.